Title-holders Entente Setif suffered a 2:1 home defeat against fellow Algerians USM Alger.
Senegal international striker Demba Ba is on the verge of joining Shanghai Shenhua
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Tunisia and Belgian coach George Leekens have parted ways.
Sudanese side Al Merreikh began the group phase with a 2:0 victory.
Etoile win as Ahly continue defence.
The three sides from Algeria, including reigning champions Entente Setif in GROUP B.
Tanzania has appointed former international Charles Boniface Mkwasa as interim coach.
Leeds United sign Ivory Coast defender Sol Bamba .
Burkina Faso striker Bertrand Traore is set to feature in Chelsea's first-team squad after being granted a work permit.
LAST SIXTEEN QUARTER-FINALS
28th June 2014
Brazil vs Chile 3:2
Brazil through on penalties.
The Selecao reached the Quarter-Finals
Hosts Brazil knock Chile out of the 2014 Fifa World Cup in the second round with a 3:2 win on penalties.
GOALS
Brasilien: 1x
18' David Luiz (#4)
Chile: 1x
32' Alexis Sánchez (#7)
Brazil
Chile